Chemistry-
General
Easy

Question

Consider the Hofmann ammonolysis reaction

If R equals C i H subscript 5 end subscript, the correct order of basic character of the above amines in aqueous median is:

  1. 2 to the power of 0 end exponent greater than 3 to the power of ring operator end exponent greater than 1 to the power of 0 end exponent greater than N H subscript 3 end subscript    
  2. 2 to the power of ring operator end exponent greater than 3 to the power of ring operator end exponent greater than 1 to the power of ring operator end exponent greater than N H subscript 3 end subscript    
  3. 3 to the power of ring operator end exponent greater than 2 to the power of ring operator end exponent greater than 1 to the power of ring operator end exponent greater than N H subscript 3 end subscript    
  4. N H subscript 3 end subscript greater than 1 to the power of ring operator end exponent greater than 2 to the power of ring operator end exponent greater than 3 to the power of ring operator end exponent    

The correct answer is: 3 to the power of ring operator end exponent greater than 2 to the power of ring operator end exponent greater than 1 to the power of ring operator end exponent greater than N H subscript 3 end subscript

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Carbene intennediates are produced by the photo lysis of diazomethane open parentheses C H subscript 2 end subscript N subscript 2 end subscript close parentheses or ketene open parentheses C H subscript 2 end subscript equals C equals 0 close parentheses. They are also produced by the reaction of C H X subscript 3 end subscript with base or by Simmons-Smith reaction. There are two types of carbenes, singlet and triplet. They are so called due to their spin state.



Carbene intennediates are produced by the photo lysis of diazomethane open parentheses C H subscript 2 end subscript N subscript 2 end subscript close parentheses or ketene open parentheses C H subscript 2 end subscript equals C equals 0 close parentheses. They are also produced by the reaction of C H X subscript 3 end subscript with base or by Simmons-Smith reaction. There are two types of carbenes, singlet and triplet. They are so called due to their spin state.



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Carbene intennediates are produced by the photo lysis of diazomethane open parentheses C H subscript 2 end subscript N subscript 2 end subscript close parentheses or ketene open parentheses C H subscript 2 end subscript equals C equals 0 close parentheses. They are also produced by the reaction of C H X subscript 3 end subscript with base or by Simmons-Smith reaction. There are two types of carbenes, singlet and triplet. They are so called due to their spin state.
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