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Metallic gold frequently is found in aluminosilicate rocks and its is finely dispersed among other minerals. It may be extracted by trating the crushed rock with aerated potassium cyanide solution. During this process metallic gold is slowly converted to [Au(CN)2 ] , which is soluble in water. After equilibrium has been reached, the aqueous phase is pumped off and the metallic gold is recovered from it by reacting the gold complex with zinc, which is converted to [Zn(CN)4 ] 2–. Gold in nature is frequently alloyed with silver which is also oxidised by aerated sodium cyanide solution. Silver occurs as native as well as sulphurised ore.
The correct reaction involved in the leaching of gold with dilute solution of NaCN is :

  1. 4 Au plus 8 CN to the power of minus plus 2 straight H subscript 2 straight O plus straight O subscript 2 left parenthesis text  air  end text right parenthesis not stretchy rightwards arrow 4 open square brackets Au left parenthesis CN right parenthesis subscript 2 close square brackets to the power of minus plus 4 OH
  2. A u plus 2 C N to the power of minus end exponent rightwards arrow A u open square brackets left parenthesis C n right parenthesis subscript 2 end subscript close square brackets    
  3. Z n plus 2 C N to the power of minus end exponent rightwards arrow Z n open square brackets left parenthesis C n right parenthesis subscript 2 end subscript close square brackets    
  4. Z n plus 4 C N to the power of minus end exponent rightwards arrow Z n open square brackets left parenthesis C n right parenthesis subscript 4 end subscript close square brackets to the power of 2 minus end exponent    

The correct answer is: 4 Au plus 8 CN to the power of minus plus 2 straight H subscript 2 straight O plus straight O subscript 2 left parenthesis text  air  end text right parenthesis not stretchy rightwards arrow 4 open square brackets Au left parenthesis CN right parenthesis subscript 2 close square brackets to the power of minus plus 4 OH

Related Questions to study

General
chemistry-

Minerals from which metals can be extracted economically and easily are called ores. The extraction of metals from theirs ores involves the following processes.
i) Concentration
ii) Calcination | roasting | leaching
iii) Reduction It is carried out by one of the following methods.

Minerals from which metals can be extracted economically and easily are called ores. The extraction of metals from theirs ores involves the following processes.
i) Concentration
ii) Calcination | roasting | leaching
iii) Reduction It is carried out by one of the following methods.

chemistry-General
General
chemistry-

The chemical composition of “slag” formed during the smelting process in the extraction of copper is :

The chemical composition of “slag” formed during the smelting process in the extraction of copper is :

chemistry-General
General
chemistry-

Native silver metal forms a water soluble complex with a dilute aqueous solution of NaCN in the presence of:

Native silver metal forms a water soluble complex with a dilute aqueous solution of NaCN in the presence of:

chemistry-General
parallel
General
chemistry-

Dow's process of extraction of Mg involves extraction of Mg from sea water. Sea water is concentrated in sun light and is then treated with slaked lime. Magnesium hydroxide is heated in a stream of HCl to give MgCl2 which is electrolysed to discharge Mg. The mixture is in the ratio 35 percent sign M g C l subscript 2 end subscript plus 50 percent sign N a C l plus 15 percent sign C a C l subscript 2 end subscript times N a C l blank a n d blank C a C l subscript 2 end subscript are added to lower the fusion temperature and to increase the conductance.
M g to the power of 2 plus end exponent plus C a left parenthesis O H right parenthesis subscript 2 end subscript ⟶ M g left parenthesis O H right parenthesis subscript 2 end subscript plus C a to the power of 2 plus end exponent
M g left parenthesis O H right parenthesis subscript 2 end subscript plus 2 H C l ⟶ M g C l subscript 2 end subscript plus 2 H subscript 2 end subscript O blank left parenthesis l i q u i d right parenthesis
Electrolysis of fused MgCl2 stack ⟶ with text  Anode  end text on top 2 C l to the power of minus end exponent ⟶ C l subscript 2 end subscript plus 2 subscript negative 1 end subscript e to the power of ring operator end exponent stack ⟶ with text  Cathode  end text on top M g to the power of 2 plus end exponent plus 2 subscript negative 1 end subscript e to the power of ring operator end exponent ⟶ M g
electrolysed is protected from atmospheric oxidation by a blanket of inert gases
In the hydrated chloride of Mg the value of of x is

Dow's process of extraction of Mg involves extraction of Mg from sea water. Sea water is concentrated in sun light and is then treated with slaked lime. Magnesium hydroxide is heated in a stream of HCl to give MgCl2 which is electrolysed to discharge Mg. The mixture is in the ratio 35 percent sign M g C l subscript 2 end subscript plus 50 percent sign N a C l plus 15 percent sign C a C l subscript 2 end subscript times N a C l blank a n d blank C a C l subscript 2 end subscript are added to lower the fusion temperature and to increase the conductance.
M g to the power of 2 plus end exponent plus C a left parenthesis O H right parenthesis subscript 2 end subscript ⟶ M g left parenthesis O H right parenthesis subscript 2 end subscript plus C a to the power of 2 plus end exponent
M g left parenthesis O H right parenthesis subscript 2 end subscript plus 2 H C l ⟶ M g C l subscript 2 end subscript plus 2 H subscript 2 end subscript O blank left parenthesis l i q u i d right parenthesis
Electrolysis of fused MgCl2 stack ⟶ with text  Anode  end text on top 2 C l to the power of minus end exponent ⟶ C l subscript 2 end subscript plus 2 subscript negative 1 end subscript e to the power of ring operator end exponent stack ⟶ with text  Cathode  end text on top M g to the power of 2 plus end exponent plus 2 subscript negative 1 end subscript e to the power of ring operator end exponent ⟶ M g
electrolysed is protected from atmospheric oxidation by a blanket of inert gases
In the hydrated chloride of Mg the value of of x is

chemistry-General
General
chemistry-

Dow's process of extraction of Mg involves extraction of Mg from sea water. Sea water is concentrated in sun light and is then treated with slaked lime. Magnesium hydroxide is heated in a stream of HCl to give MgCl2 which is electrolysed to discharge Mg. The mixture is in the ratio 35 percent sign M g C l subscript 2 end subscript plus 50 percent sign N a C l plus 15 percent sign C a C l subscript 2 end subscript times N a C l blank a n d blank C a C l subscript 2 end subscript are added to lower the fusion temperature and to increase the conductance.
M g to the power of 2 plus end exponent plus C a left parenthesis O H right parenthesis subscript 2 end subscript ⟶ M g left parenthesis O H right parenthesis subscript 2 end subscript plus C a to the power of 2 plus end exponent
M g left parenthesis O H right parenthesis subscript 2 end subscript plus 2 H C l ⟶ M g C l subscript 2 end subscript plus 2 H subscript 2 end subscript O blank left parenthesis l i q u i d right parenthesis
Electrolysis of fused MgCl2
electrolysed is protected from atmospheric oxidation by a blanket of inert gases.
M g to the power of 2 plus end exponent plus C a left parenthesis O H right parenthesis subscript 2 end subscript ⟶ M g left parenthesis O H right parenthesis subscript 2 end subscript downwards arrow plus C a to the power of 2 plus end exponent2 This reaction indicates :

Dow's process of extraction of Mg involves extraction of Mg from sea water. Sea water is concentrated in sun light and is then treated with slaked lime. Magnesium hydroxide is heated in a stream of HCl to give MgCl2 which is electrolysed to discharge Mg. The mixture is in the ratio 35 percent sign M g C l subscript 2 end subscript plus 50 percent sign N a C l plus 15 percent sign C a C l subscript 2 end subscript times N a C l blank a n d blank C a C l subscript 2 end subscript are added to lower the fusion temperature and to increase the conductance.
M g to the power of 2 plus end exponent plus C a left parenthesis O H right parenthesis subscript 2 end subscript ⟶ M g left parenthesis O H right parenthesis subscript 2 end subscript plus C a to the power of 2 plus end exponent
M g left parenthesis O H right parenthesis subscript 2 end subscript plus 2 H C l ⟶ M g C l subscript 2 end subscript plus 2 H subscript 2 end subscript O blank left parenthesis l i q u i d right parenthesis
Electrolysis of fused MgCl2
electrolysed is protected from atmospheric oxidation by a blanket of inert gases.
M g to the power of 2 plus end exponent plus C a left parenthesis O H right parenthesis subscript 2 end subscript ⟶ M g left parenthesis O H right parenthesis subscript 2 end subscript downwards arrow plus C a to the power of 2 plus end exponent2 This reaction indicates :

chemistry-General
General
chemistry-

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
What is wrong if anode is made of nickel instead of graphite?

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
What is wrong if anode is made of nickel instead of graphite?

chemistry-General
parallel
General
chemistry-

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
The molten electrolytes contains N a to the power of plus end exponent comma A l to the power of 3 plus end exponent comma C a to the power of 2 plus end exponentbut only Al gets deposited at cathode because :

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
The molten electrolytes contains N a to the power of plus end exponent comma A l to the power of 3 plus end exponent comma C a to the power of 2 plus end exponentbut only Al gets deposited at cathode because :

chemistry-General
General
chemistry-

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
The function of fluorspar (CaF2) is :

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
The function of fluorspar (CaF2) is :

chemistry-General
General
chemistry-

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite)
Cathode : Graphite inside the Fe container
Anode : Graphite rods
Coke powder is spreaded over the molten electrolyte due to :

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite)
Cathode : Graphite inside the Fe container
Anode : Graphite rods
Coke powder is spreaded over the molten electrolyte due to :

chemistry-General
parallel
General
chemistry-

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
The purpose of adding cryolite is :

Extraction of Aluminium can be understand by :  electrolytic reduction of Al2O3
Electrolyte : (Al2O3 + Cryolite) .
Cathode : Graphite inside the Fe container
Anode : Graphite rods
The purpose of adding cryolite is :

chemistry-General
General
chemistry-


Which of the following statement is true ?


Which of the following statement is true ?

chemistry-General
General
chemistry-


To make the following reduction process spontaneous, temperature should be : Z n O plus C ⟶ Z n plus C O


To make the following reduction process spontaneous, temperature should be : Z n O plus C ⟶ Z n plus C O

chemistry-General
parallel
General
chemistry-

chemistry-General
General
chemistry-

Metallic gold frequently is found in aluminosilicate rocks and it is finely dispersed among other minerals. It may be extracted by treating the crushed rock with aerated sodium cyanide solution. During this process metallic gold is slowly converted to open square brackets A u left parenthesis C N right parenthesis subscript 2 end subscript close square brackets to the power of minus end exponent, which is soluble in water. After equilibrium has been reached, the aqueous phase is pumped off and the metallic gold is recovered from it by reacting the gold complex with zinc, which is converted to open square brackets Z n left parenthesis C N right parenthesis subscript 2 end subscript close square brackets to the power of 2 minus end exponentGold in nature is frequently alloyed with silver which is also oxidised by aerated sodium cyanide solution.
There have been several efforts to develop alternative gold extraction processes which could replace this one. Why ?

Metallic gold frequently is found in aluminosilicate rocks and it is finely dispersed among other minerals. It may be extracted by treating the crushed rock with aerated sodium cyanide solution. During this process metallic gold is slowly converted to open square brackets A u left parenthesis C N right parenthesis subscript 2 end subscript close square brackets to the power of minus end exponent, which is soluble in water. After equilibrium has been reached, the aqueous phase is pumped off and the metallic gold is recovered from it by reacting the gold complex with zinc, which is converted to open square brackets Z n left parenthesis C N right parenthesis subscript 2 end subscript close square brackets to the power of 2 minus end exponentGold in nature is frequently alloyed with silver which is also oxidised by aerated sodium cyanide solution.
There have been several efforts to develop alternative gold extraction processes which could replace this one. Why ?

chemistry-General
General
chemistry-

Statement-1 :Lead, tin and bismuth are purified by liquation method.
Statement-2 : Lead, tin and bismuth have low m.p. as compared to impurities

Statement-1 :Lead, tin and bismuth are purified by liquation method.
Statement-2 : Lead, tin and bismuth have low m.p. as compared to impurities

chemistry-General
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