Question
Symmetrically substituted epoxides give the same products in both the acid catalysed and base catalyzed ring opening. An unsymmetrical epoxide gives different products under acid catalysed and base catalysed conditions. Under basic conditions, the alkoxide ion simply attacks the less hindered carbon atom in an 2 displacement. Under acidic conditions, the alcohol, attacks the protonated epoxide
Structure II and III show that the oxirane carbon share part of positive charge. The tertiary carbon bear a larger part of positive charge and it is more strongly electrophilic. The bond between tertiary carbon and oxygen is weaker implying a lower transition state energy for attack at the tertiary carbon. Attack by the weak nucleophilic is sensitive to the strength of electrophilic is sensitive to the strength of electrophile. Centre attack takes place at more electrophilic carbon which is usually the more substituted carbon because it can better support the positive charge
What will be the products in following reactions
The correct answer is:
Related Questions to study
Alcohols undergo acid catalysed elimination reactions to produce alkenes. Because water is lost in the elimination, this reaction is called dehydration reaction. Secondary and tertiary alcohols always give E1 reaction in dehydration. Primary alcohols whose b-carbon is branched also give E1 reaction. The reactivity of alcohol for elimination reaction is tertiary alcohol > Secondary alcohol > Primary alcohol
Identify the product in the given reaction :
Alcohols undergo acid catalysed elimination reactions to produce alkenes. Because water is lost in the elimination, this reaction is called dehydration reaction. Secondary and tertiary alcohols always give E1 reaction in dehydration. Primary alcohols whose b-carbon is branched also give E1 reaction. The reactivity of alcohol for elimination reaction is tertiary alcohol > Secondary alcohol > Primary alcohol
Identify the product in the given reaction :
What are the products of the following reaction ?
What are the products of the following reaction ?
A given ray of light suffers minimum deviation in an equileteral prism ‘P’. Additional prisms Q and R of identical shape and of the same material as ‘P’ are now added. The ray will now suffer
A given ray of light suffers minimum deviation in an equileteral prism ‘P’. Additional prisms Q and R of identical shape and of the same material as ‘P’ are now added. The ray will now suffer
'U' shaped wire is placed in front of a concave mirror of radius of curvature 20cm as shown. The total length of the image of the wire ABCD is nearly
'U' shaped wire is placed in front of a concave mirror of radius of curvature 20cm as shown. The total length of the image of the wire ABCD is nearly
Find the values of x and y.
If your answers are not integers, it should be in simplest radical form.
For such questions, we should know about the properties of a right-angled triangle and 30°-60°-90° triangle. The alternate way to solve the above question is by Pythagoras theorem and trigonometric ratios.
Find the values of x and y.
If your answers are not integers, it should be in simplest radical form.
For such questions, we should know about the properties of a right-angled triangle and 30°-60°-90° triangle. The alternate way to solve the above question is by Pythagoras theorem and trigonometric ratios.
Find the length of the hypotenuse. leave your answer in simplest radical form.
For such questions, we should know the properties of different triangles.
Find the length of the hypotenuse. leave your answer in simplest radical form.
For such questions, we should know the properties of different triangles.
he dependence of nuclear force on distance between nucleons is not known precisely, but approximate variation is shown graphically From graph which of following statements cannot be concluded?
he dependence of nuclear force on distance between nucleons is not known precisely, but approximate variation is shown graphically From graph which of following statements cannot be concluded?
The floral formula, Ebr belong to family -
The floral formula, Ebr belong to family -
The floral formula belongs to plant -
The floral formula belongs to plant -
Identify the special triangle given below.
We should know different properties of right-angled triangle. We should also know about the different types of triangles.
Identify the special triangle given below.
We should know different properties of right-angled triangle. We should also know about the different types of triangles.