Chemistry-
General
Easy

Question

Electrophiles are :

  1. Lewis acides    
  2. Lewis bases    
  3. Bronsted acids    
  4. Bronsted bases    

The correct answer is: Lewis acides

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Hydrogenation of alkenes and alkynes takes place in presence of certain catalysts. In Sabatier Senderen’s reaction, the addition of hydrogen takes place in presence of Raney nickel catalyst. Platinum and palladium can also be used catalyst in these reactions. These are heterogeneous catalyst and used in finely divided state. Experimentally, it is observed that less crowded alkenes absorb H2 with faster rate. Controlled hydrogenation of alkyne in presence of Lindlar’s catalyst yields cis product i.e., ‘cis’ alkene. Thus, in presence of Lindlar’s catalyst ‘syn’ addition takes place. The relative rate of hydrogenation follows the order

Non-terminal alkynes are reduced in presence of Na or Li metal dissolved in liquid ammonia. In this reaction, anti-addition of hydrogen results into the trans-product.
The product of the following reaction is :

Hydrogenation of alkenes and alkynes takes place in presence of certain catalysts. In Sabatier Senderen’s reaction, the addition of hydrogen takes place in presence of Raney nickel catalyst. Platinum and palladium can also be used catalyst in these reactions. These are heterogeneous catalyst and used in finely divided state. Experimentally, it is observed that less crowded alkenes absorb H2 with faster rate. Controlled hydrogenation of alkyne in presence of Lindlar’s catalyst yields cis product i.e., ‘cis’ alkene. Thus, in presence of Lindlar’s catalyst ‘syn’ addition takes place. The relative rate of hydrogenation follows the order

Non-terminal alkynes are reduced in presence of Na or Li metal dissolved in liquid ammonia. In this reaction, anti-addition of hydrogen results into the trans-product.
The product of the following reaction is :

Chemistry-General
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Hydrogenation of alkenes and alkynes takes place in presence of certain catalysts. In Sabatier Senderen’s reaction, the addition of hydrogen takes place in presence of Raney nickel catalyst. Platinum and palladium can also be used catalyst in these reactions. These are heterogeneous catalyst and used in finely divided state. Experimentally, it is observed that less crowded alkenes absorb H2 with faster rate. Controlled hydrogenation of alkyne in presence of Lindlar’s catalyst yields cis product i.e., ‘cis’ alkene. Thus, in presence of Lindlar’s catalyst ‘syn’ addition takes place. The relative rate of hydrogenation follows the order

Non-terminal alkynes are reduced in presence of Na or Li metal dissolved in liquid ammonia. In this reaction, anti-addition of hydrogen results into the trans-product.
In which of the following cases, the reaction is most exothermic?

Hydrogenation of alkenes and alkynes takes place in presence of certain catalysts. In Sabatier Senderen’s reaction, the addition of hydrogen takes place in presence of Raney nickel catalyst. Platinum and palladium can also be used catalyst in these reactions. These are heterogeneous catalyst and used in finely divided state. Experimentally, it is observed that less crowded alkenes absorb H2 with faster rate. Controlled hydrogenation of alkyne in presence of Lindlar’s catalyst yields cis product i.e., ‘cis’ alkene. Thus, in presence of Lindlar’s catalyst ‘syn’ addition takes place. The relative rate of hydrogenation follows the order

Non-terminal alkynes are reduced in presence of Na or Li metal dissolved in liquid ammonia. In this reaction, anti-addition of hydrogen results into the trans-product.
In which of the following cases, the reaction is most exothermic?

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Chlorination of methane involves three steps: chain-initiating, chain-propagating and chain-terminating.

When oxygen is passed through the reaction mixture, chlorination of methane slows down temporarily
Although chlorination of methane is an exothermic, the reaction requires high temperature because

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When oxygen is passed through the reaction mixture, chlorination of methane slows down temporarily
Although chlorination of methane is an exothermic, the reaction requires high temperature because

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Chlorination of methane involves three steps: chain-initiating, chain-propagating and chain-terminating.

When oxygen is passed through the reaction mixture, chlorination of methane slows down temporarily
Chain-terminating step may involve the formation of

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When oxygen is passed through the reaction mixture, chlorination of methane slows down temporarily
Chain-terminating step may involve the formation of

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When oxygen is passed through the reaction mixture, chlorination of methane slows down temporarily
Chain-propagating steps

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When oxygen is passed through the reaction mixture, chlorination of methane slows down temporarily
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