Chemistry-
General
Easy

Question

Reactivity of M e M g B r with the following in the decreasing order is:
i)
ii)
iii)
iv) 

  1. (i)>(ii)>(iii)>(iv)    
  2. (iv)>(i)>(ii)>(iii)    
  3. (i)>(iii)>(ii)>(iv)    
  4. (iv)>(ii)>(iii)>(i)    

The correct answer is: (iv)>(i)>(ii)>(iii)


    The order of reactivity of G.R. with different functional groups is aliphatic aldehyde > aromatic > aldehyde >aliphatic ketone > aromatic ketone. Also, EWG favours NA reaction
    iv.is aliphatic ketone withnegative I effect of Ph group. (+R effect is not possible since the double bond of benzene ring is not in conjugation with (C=O) group. So, (iv) is the most reactive ketone
    Hence, the order is i v greater than i greater than blank i i greater than i i i

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