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What is the product in following cross Claisen condensation?
straight C subscript 2 straight H subscript 5 COOC subscript 2 straight H subscript 5 plus stack COOC subscript 2 straight H subscript 5 with COOC subscript 2 straight H subscript 5 below fraction numerator straight C subscript 2 straight H subscript 5 ONa over denominator straight H to the power of plus end fraction not stretchy rightwards arrow ?

The correct answer is:

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Match the columns
Column-I                                              Column-II
A) Coordinated water                                     (p)open square brackets Cu open parentheses straight H subscript 2 straight O close parentheses subscript 4 close square brackets to the power of 4 plus end exponent SO subscript 4 superscript 2 minus end superscript times straight H subscript 2 straight O
B) Interstitial water                                         (q)straight C subscript 17 straight H subscript 35 COONa
C) Hydrogen-bonded water                            (r)BaCl subscript 2 times 2 straight H subscript 2 straight O
(s)open square brackets Cr open parentheses straight H subscript 2 straight O close parentheses subscript 6 close square brackets to the power of 3 plus end exponent 3 Cl to the power of minus

Match the columns
Column-I                                              Column-II
A) Coordinated water                                     (p)open square brackets Cu open parentheses straight H subscript 2 straight O close parentheses subscript 4 close square brackets to the power of 4 plus end exponent SO subscript 4 superscript 2 minus end superscript times straight H subscript 2 straight O
B) Interstitial water                                         (q)straight C subscript 17 straight H subscript 35 COONa
C) Hydrogen-bonded water                            (r)BaCl subscript 2 times 2 straight H subscript 2 straight O
(s)open square brackets Cr open parentheses straight H subscript 2 straight O close parentheses subscript 6 close square brackets to the power of 3 plus end exponent 3 Cl to the power of minus

ChemistryGeneral
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Chemistry

Match the columns.
Column I                                                  Column II
text  A)  end text fraction numerator p K subscript a comma H subscript 2 O plus p K subscript b comma H subscript 2 end subscript O end subscript over denominator 2 end fraction text  at  end text 25 to the power of ring operator C open parentheses d subscript text water  end text end subscript equals 1.0 straight g divided by ml close parentheses     text  (P)  end text fraction numerator straight p K subscript straight w over denominator 2 end fraction
text  B)  end text pH text  of  end text CH subscript 3 COONH subscript 4 left parenthesis aq right parenthesis open parentheses K subscript straight a comma CH comma straight c straight infinity OH end subscript equals K subscript straight b comma NH comma OH end subscript close parentheses    text  (Q)  end text 16 minus log invisible function application 1.8
text  C)  end text pH text  of pure water at  end text 320 straight K text  .  end text                                      left parenthesis straight R right parenthesis minus log invisible function application K subscript straight a comma straight H comma O end subscript
text  (S)  end text less than 7.0

Match the columns.
Column I                                                  Column II
text  A)  end text fraction numerator p K subscript a comma H subscript 2 O plus p K subscript b comma H subscript 2 end subscript O end subscript over denominator 2 end fraction text  at  end text 25 to the power of ring operator C open parentheses d subscript text water  end text end subscript equals 1.0 straight g divided by ml close parentheses     text  (P)  end text fraction numerator straight p K subscript straight w over denominator 2 end fraction
text  B)  end text pH text  of  end text CH subscript 3 COONH subscript 4 left parenthesis aq right parenthesis open parentheses K subscript straight a comma CH comma straight c straight infinity OH end subscript equals K subscript straight b comma NH comma OH end subscript close parentheses    text  (Q)  end text 16 minus log invisible function application 1.8
text  C)  end text pH text  of pure water at  end text 320 straight K text  .  end text                                      left parenthesis straight R right parenthesis minus log invisible function application K subscript straight a comma straight H comma O end subscript
text  (S)  end text less than 7.0

ChemistryGeneral
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Chemistry

Match the columns.    
              Column I                                                      Column II
A) NaCl                                                   (P) Cationic hydrolysis
B) Na2CO3                                              (Q) Anionic hydrolysis
C) NH4Cl                                                 (R) pH = 7.0 at 25oC
D) CH3COONH4                                      (S) pH < 7.0 at 25oC
(T) pH > 7.0 at 25oC
Ka, CH3COOH  = Kb, NH4OH

Match the columns.    
              Column I                                                      Column II
A) NaCl                                                   (P) Cationic hydrolysis
B) Na2CO3                                              (Q) Anionic hydrolysis
C) NH4Cl                                                 (R) pH = 7.0 at 25oC
D) CH3COONH4                                      (S) pH < 7.0 at 25oC
(T) pH > 7.0 at 25oC
Ka, CH3COOH  = Kb, NH4OH

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Column I (pH value)                                                     Column II (Solution)
A) 5.0                                               (P) pH at which Mg(OH)2 just start precipitating                                                                       from 2.0×10−3 M-Mg2+ solution (Ksp of Mg(OH)2                                                                  = 2 × 10−6 M3 ).
B) 9.0                                              (Q) Maximum pH at which 0.1 mole of Al(OH)3                                                                     dissolves completely as Al3+ in 1 L solution (Ksp                                                                           of  Al(OH)3 = 1 × 10−28 M4).
C) 12.5                                            (R) pH at which 0.1 M-CH3COOH dissociates                                                             1000/11% (Ka of CH3COOH = 1.0×10−5M).
D) 6.0                                              (S) pH of 0.001 M-HA (weak acid) solution (pKa of                                                             HA = pKb of A).
(T) pH of 3×10−5 M-CaA2 solution (CaA2 dissociates                                                             completely in water; Ka of HA = 5 × 10−9).
 

Column I (pH value)                                                     Column II (Solution)
A) 5.0                                               (P) pH at which Mg(OH)2 just start precipitating                                                                       from 2.0×10−3 M-Mg2+ solution (Ksp of Mg(OH)2                                                                  = 2 × 10−6 M3 ).
B) 9.0                                              (Q) Maximum pH at which 0.1 mole of Al(OH)3                                                                     dissolves completely as Al3+ in 1 L solution (Ksp                                                                           of  Al(OH)3 = 1 × 10−28 M4).
C) 12.5                                            (R) pH at which 0.1 M-CH3COOH dissociates                                                             1000/11% (Ka of CH3COOH = 1.0×10−5M).
D) 6.0                                              (S) pH of 0.001 M-HA (weak acid) solution (pKa of                                                             HA = pKb of A).
(T) pH of 3×10−5 M-CaA2 solution (CaA2 dissociates                                                             completely in water; Ka of HA = 5 × 10−9).
 

ChemistryGeneral
General
Chemistry

A ketone reacted with straight C subscript 2 straight H subscript 5 MgBr reagent followed by hydrolysis gave a product which on dehydration gives an alkene. The alkene on ozonolysis gave diethyl ketone and acetaldehyde. The ketone is:

A ketone reacted with straight C subscript 2 straight H subscript 5 MgBr reagent followed by hydrolysis gave a product which on dehydration gives an alkene. The alkene on ozonolysis gave diethyl ketone and acetaldehyde. The ketone is:

ChemistryGeneral
General
Chemistry

Consider the reaction:

R CHO plus NH subscript 2 NH subscript 2 not stretchy rightwards arrow R CH equals straight N minus NH subscript 2
What sort of reaction is it?

Consider the reaction:

R CHO plus NH subscript 2 NH subscript 2 not stretchy rightwards arrow R CH equals straight N minus NH subscript 2
What sort of reaction is it?

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General
Chemistry

CH subscript 3 COOH not stretchy ⟶ with LiAlH subscript 4 on top straight A plus CH subscript 3 COOH not stretchy ⟶ with straight H subscript 3 straight O to the power of plus on top straight B plus straight H subscript 2 straight O
In the above reactions ‘A’ and ‘B’ respectively are

CH subscript 3 COOH not stretchy ⟶ with LiAlH subscript 4 on top straight A plus CH subscript 3 COOH not stretchy ⟶ with straight H subscript 3 straight O to the power of plus on top straight B plus straight H subscript 2 straight O
In the above reactions ‘A’ and ‘B’ respectively are

ChemistryGeneral
General
Chemistry

Amides may be converted into amines by reaction named after:

Amides may be converted into amines by reaction named after:

ChemistryGeneral
General
Chemistry

Carboxylic acids dissolve in  NaOH because the acids undergo:

Carboxylic acids dissolve in  NaOH because the acids undergo:

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General
Chemistry

0.20 g of a hydrocarbon on combustion gave 0.66 g CO2 .The percentage of hydrogen in the hydrocarbon is about :

0.20 g of a hydrocarbon on combustion gave 0.66 g CO2 .The percentage of hydrogen in the hydrocarbon is about :

ChemistryGeneral
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Chemistry

ChemistryGeneral
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Chemistry

Match the columns.

Column I

Column II

A)
 H subscript 2 left parenthesis g right parenthesis plus I subscript 2 left parenthesis g right parenthesis not stretchy rightwards harpoon over leftwards harpoon 2 HI left parenthesis g right parenthesis P)
Unaffected by inert gas addition
B)
 CaCO subscript 3 left parenthesis s right parenthesis not stretchy rightwards harpoon over leftwards harpoon CaO left parenthesis s right parenthesis plus CO subscript 2 left parenthesis g right parenthesis Q)
Forward shift by rise in pressure and backward shift by inert gas
addition.
C)
 N subscript 2 left parenthesis g right parenthesis plus 3 H subscript 2 left parenthesis g right parenthesis not stretchy rightwards harpoon over leftwards harpoon 2 NH subscript 3 left parenthesis g right parenthesis R)
Unaffected by increase in pressure.
D)
 PCl subscript 5 left parenthesis g right parenthesis not stretchy rightwards harpoon over leftwards harpoon PCl subscript 3 left parenthesis g right parenthesis plus Cl subscript 2 left parenthesis g right parenthesis S)
Backward shift by rise in pressure and forward shift by inert gas addition.

Match the columns.

Column I

Column II

A)
 H subscript 2 left parenthesis g right parenthesis plus I subscript 2 left parenthesis g right parenthesis not stretchy rightwards harpoon over leftwards harpoon 2 HI left parenthesis g right parenthesis P)
Unaffected by inert gas addition
B)
 CaCO subscript 3 left parenthesis s right parenthesis not stretchy rightwards harpoon over leftwards harpoon CaO left parenthesis s right parenthesis plus CO subscript 2 left parenthesis g right parenthesis Q)
Forward shift by rise in pressure and backward shift by inert gas
addition.
C)
 N subscript 2 left parenthesis g right parenthesis plus 3 H subscript 2 left parenthesis g right parenthesis not stretchy rightwards harpoon over leftwards harpoon 2 NH subscript 3 left parenthesis g right parenthesis R)
Unaffected by increase in pressure.
D)
 PCl subscript 5 left parenthesis g right parenthesis not stretchy rightwards harpoon over leftwards harpoon PCl subscript 3 left parenthesis g right parenthesis plus Cl subscript 2 left parenthesis g right parenthesis S)
Backward shift by rise in pressure and forward shift by inert gas addition.

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General
Chemistry

In Gattermann Koch reactionthe product formed is

In Gattermann Koch reactionthe product formed is

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Chemistry

Which one of the following has no stereogenic center?

Which one of the following has no stereogenic center?

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