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Question

Homolytic bond fission of a covalent single bond gives rise to free radicals. Owing to the presence of an odd electron, free radicals are highly reactive. They have planar to pyramidal geometry depending upon the groups attached to the C-atom having odd electron. Alkyl free radicals are stabilised by hyperconjugation whereas allyl and benzyl free radicals are stabilised by resonance. They are formed as intermediates in the reaction mixture either in the gaseous phase or in non-polar solvents. Addition of HBr to alkenes in presence of peroxide, the substitution of allylic or benzylic hydrogen by ‘Cl’ at high temperature or by ‘Br’ in presence of NBS are examples of reactions involving free radical intermediates.
3, 5–dimethylcyclopentene reacts with N–bromosuccinimide (NBS) in CCl4 in presence of light or peroxide. Identify the product.

  1.    
  2.    
  3.    
  4.    

The correct answer is:

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