Chemistry-
General
Easy
Question
In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :
Mechanism :
If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
- B & C both are correct
The correct answer is:
Hoffmann rearrangement is 100% intramolecular. one amide will give only one amine with Br2/OHQ
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In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :
Mechanism :
If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
Arrange the following amides according to their relative reactivity when reacted with Br2 in excess of strong base
I) 
II) 
III) 
IV) 
In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :
Mechanism :
If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
Arrange the following amides according to their relative reactivity when reacted with Br2 in excess of strong base
I)
II)
III)
IV)
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