Chemistry-
General
Easy

Question

In which of the following pairs both the complexes show optical isomerism ?

  1. cis- open square brackets C r open parentheses C subscript 2 end subscript O subscript 4 end subscript close parentheses subscript 2 end subscript C l subscript 2 end subscript close square brackets to the power of 3 minus end exponent, cis- open square brackets Co open parentheses NH subscript 3 close parentheses subscript 4 close square brackets subscript 2    
  2. open square brackets C o left parenthesis e n right parenthesis subscript 3 end subscript close square brackets C l subscript 3 end subscript comma c i s minus open square brackets C o left parenthesis e n right parenthesis subscript 2 end subscript C l subscript 2 end subscript close square brackets C l    
  3. left square bracket P t C l (dien) right square bracket C l, open square brackets N i C l subscript 2 end subscript B r subscript 2 end subscript close square brackets to the power of 2 minus end exponent    
  4. open square brackets C o open parentheses N O subscript 3 end subscript close parentheses subscript 3 end subscript open parentheses N H subscript 3 end subscript close parentheses subscript 3 end subscript close square brackets, cis-open square brackets Pt left parenthesis en right parenthesis subscript 2 Cl subscript 2 close square brackets    

The correct answer is: open square brackets C o left parenthesis e n right parenthesis subscript 3 end subscript close square brackets C l subscript 3 end subscript comma c i s minus open square brackets C o left parenthesis e n right parenthesis subscript 2 end subscript C l subscript 2 end subscript close square brackets C l

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