Chemistry-
General
Easy
Question
The equilibrium in aqueous medium at 25°C shifts towards the left in the presence of :
-
-
- SCN–
- CN–
The correct answer is:
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Oxygen differs from the otehr elements of the group. Compounds of oxygen with metals are more ionic in nature and hydrogen bonding is more important for oxygen compounds. Oxygen is never more than divalent because when it has formed two covalent bonds, there are no low energy orbitals which can be used to form further bonds. However, the elements S, Se, Te and Po have empty d-orbitals which may be used for bonding and they can form four or six bonds by unpairing eletctrons. However, the higher oxidation states becomes less stable on descending the group. p - dpThe bond between S and O or Se and O, are much shorter than might be expected for a single bond owing to p interaction between the p-orbital of oxygen and d-orbital of S or Se.
Which of the following statement is incorrect?
Oxygen differs from the otehr elements of the group. Compounds of oxygen with metals are more ionic in nature and hydrogen bonding is more important for oxygen compounds. Oxygen is never more than divalent because when it has formed two covalent bonds, there are no low energy orbitals which can be used to form further bonds. However, the elements S, Se, Te and Po have empty d-orbitals which may be used for bonding and they can form four or six bonds by unpairing eletctrons. However, the higher oxidation states becomes less stable on descending the group. p - dpThe bond between S and O or Se and O, are much shorter than might be expected for a single bond owing to p interaction between the p-orbital of oxygen and d-orbital of S or Se.
Which of the following statement is incorrect?
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Statement - 1 : Reddish brown gas, NO2 when passed through alkalies gives nitrite only.
Statement – 2 : NO2 is acidic in nature and is a mixed anhydride of nitric and nitrous acids.
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Statement – 2 : NO2 is acidic in nature and is a mixed anhydride of nitric and nitrous acids.
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Identify the incorrect statement with respect to ozone
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The property of hydrides of p–block elements mostly depends on :
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Which one is the weakest acid among the following ? I</span
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i) electronegativity difference between central atom and hydrogen
ii) size of central atom
iii) number of valence electrons in central atom Some undergo hydrolysis in which central atom is less electronegative, react with OH– to give hydrogen While acidic property of hydride in a period depends on electronegativity of central atoms, iemore electronegative is the n a group, acidic property is proportional to size of central atom Some electronIatom, more acidic is hydride deficient hydride behaves as Lewis acid while only one hydride of an element in p–block behaves as Lewis base with lone pair of electrons Hydrides in which central atom’s electronegativity is close to hydrogen has no reaction with water
Which one is the weakest acid among the following ? I</span
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The small size and high charge of Al3+ ion gives it a high charge density which is responsible for its tendency to show (a) covalency in its compounds in the gaseous state (b) high hydration energy which stabilizes its compounds in Solution, and (c) high lattice energy of its compounds in the Sol. id state Thus aluminium can forms both covalent and ionic bond Like halides of boron, halides of aluminium do not show back bonding because of increase in size of aluminium Actually aluminium atoms complete their octets by forming dimers Thus chloride and bromide of aluminium exist as dimers, both in the vapour state and in polar-Sol. vents like benzene while the corresponding boron halides exists as monomer In boron trihalides the extent of back bonding decreases with increase in size of halogens and thus lewis acid character increases All BX3 are hydroly sed by water but BF3 shows a different behavior.
Which one of the following statements is correct ?
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Which one of the following statements is correct ?
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The diagram shows three infinitely long uniform line charges placed on the X, Y and Z axis. The work done in moving a unit positive charge from (1, 1, 1) to (0, 1, 1) is equal to
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A unit positive point charge of mass m is projected with a velocity V inside the tunnel as shown. The tunnel has been made inside a uniformly charged non conducting sphere. The minimum velocity with which the point charge should be projected such it can it reach the opposite end of the tunnel, is equal to
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