Physics-
General
Easy

Question

A particle starts from a point P at a distance of A/2 from the mean position O & travels towards left as shown in the figure. If the time period of SHM, executed about O is T and amplitude A then the equation of motion of particle is :

  1. x equals A s i n invisible function application open parentheses fraction numerator 2 pi over denominator T end fraction t plus fraction numerator pi over denominator 6 end fraction close parentheses    
  2. x equals A s i n invisible function application open parentheses fraction numerator 2 pi over denominator T end fraction t plus fraction numerator 5 pi over denominator 6 end fraction close parentheses    
  3. x equals A c o s invisible function application open parentheses fraction numerator 2 pi over denominator T end fraction t plus fraction numerator pi over denominator 6 end fraction close parentheses    
  4. x equals A c o s invisible function application open parentheses fraction numerator 2 pi over denominator T end fraction t plus fraction numerator pi over denominator 3 end fraction close parentheses    

The correct answer is: x equals A s i n invisible function application open parentheses fraction numerator 2 pi over denominator T end fraction t plus fraction numerator pi over denominator 6 end fraction close parentheses

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The correct order of hybridization of the central atom in the following species N H subscript 3 end subscript comma open square brackets P t C l subscript 4 end subscript close square brackets to the power of 2 minus end exponent P C l subscript 5 end subscript superscript minus end superscript and B C l subscript 3 end subscript is (At. No. Pt = 78)

The correct order of hybridization of the central atom in the following species N H subscript 3 end subscript comma open square brackets P t C l subscript 4 end subscript close square brackets to the power of 2 minus end exponent P C l subscript 5 end subscript superscript minus end superscript and B C l subscript 3 end subscript is (At. No. Pt = 78)

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A complex compound of cobalt has molecular formula containing five N H subscript 3 end subscript molecules, one nitro group and two chlorine atoms for one Co atom. one mole of this compound produces three mole ions in aq. Solution. On reacting with excess of A g N O subscript 3 end subscript solution, two moles of AgCl get precipitated. The ionic formula of the compound is

A complex compound of cobalt has molecular formula containing five N H subscript 3 end subscript molecules, one nitro group and two chlorine atoms for one Co atom. one mole of this compound produces three mole ions in aq. Solution. On reacting with excess of A g N O subscript 3 end subscript solution, two moles of AgCl get precipitated. The ionic formula of the compound is

chemistry-General
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In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :

Mechanism :

If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
Which of the following compound(s) cannot give Hoffmann rearrangement :

In the Hofmann rearrangement an unsubstituted amide is treated with sodium hydroxide and bromine to give a primary amine that has one carbon lesser than starting amide.
General reaction :

Mechanism :

If the migrating group is chiral then its configuration is retained. Electron releasing effects in the migrating group increases reactivity of Hofmann rearrangement.
Which of the following compound(s) cannot give Hoffmann rearrangement :

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Statement-I : The order of base catalysed hydrolysis of ester is
1) C H subscript 3 end subscript minus C O O C H subscript 3 end subscript greater than C H subscript 3 end subscript minus C O O C subscript 2 end subscript H subscript 5 end subscript greater than C H subscript 3 end subscript minus C O O C H open parentheses C H subscript 3 end subscript close parentheses subscript 2 end subscript
2) 
Statement-II : S subscript N to the power of 2 end exponent end subscript The reaction is sterically as well as electronically controlled reaction.

Statement-I : The order of base catalysed hydrolysis of ester is
1) C H subscript 3 end subscript minus C O O C H subscript 3 end subscript greater than C H subscript 3 end subscript minus C O O C subscript 2 end subscript H subscript 5 end subscript greater than C H subscript 3 end subscript minus C O O C H open parentheses C H subscript 3 end subscript close parentheses subscript 2 end subscript
2) 
Statement-II : S subscript N to the power of 2 end exponent end subscript The reaction is sterically as well as electronically controlled reaction.

chemistry-General
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Select the correct statement.

Select the correct statement.

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X is :

X is :

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X is :

X is :

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Identify final product in the following reaction

Identify final product in the following reaction

chemistry-General
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Which of the following is correct order of esterification of following acids with CH3OH :
I) HCOOH
II) C H subscript 3 end subscript C O O H
III) C H subscript 3 end subscript minus C H subscript 2 end subscript minus C O O H
IV) 

Which of the following is correct order of esterification of following acids with CH3OH :
I) HCOOH
II) C H subscript 3 end subscript C O O H
III) C H subscript 3 end subscript minus C H subscript 2 end subscript minus C O O H
IV) 

chemistry-General
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The product (Q) is

The product (Q) is

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 In this reaction the product (E) is :

 In this reaction the product (E) is :

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would be : (A)

would be : (A)

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X is :

X is :

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Esterification of the acid (P) with the alcohol (Q) will gives

Esterification of the acid (P) with the alcohol (Q) will gives

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Identify the final product in the following sequence of reaction.

Identify the final product in the following sequence of reaction.

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