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Easy

Question

1 mole of N2O4 (g) at 300 K is kept in dosed container under 1 atm. It is heated to 600K when 20% mass of N2O4(g) decomposes to NO2(g). The resultant pressure is

  1. 1.2 atm    
  2. 2.4 atm    
  3. 2 atm    
  4. 1 atm    

The correct answer is: 2.4 atm

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If the minimum value of the expression y equals left parenthesis 27 right parenthesis to the power of cos invisible function application x end exponent plus left parenthesis 81 right parenthesis to the power of sin invisible function application x end exponentcan be expressed in the form square root of awhere a, b N and are in their lowest term then the value of (a + b) equals

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integral fraction numerator s i n invisible function application 12 theta minus s i n invisible function application 9 theta over denominator 2 c o s invisible function application 7 theta minus 1 end fraction d theta equals to

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The removal of two atoms or groups, one generally hydrogen open parentheses H to the power of plus end exponent close parentheses and the other a leaving group open parentheses L to the power of minus end exponent close parentheses resulting in the formation of unsaturated compound is known as elimination reaction.

In E subscript 1 end subscript (elimination) reactions, the C minus L bond is broken heterolytic ally (in step 1) to form a carbocation (as in S subscript N to the power of 1 end exponent end subscript reaction) in which open parentheses L to the power of minus end exponent close) is lost (rate determining step). The carbocation (in step 2) loses a proton from the beta-carbon atom by a base (nucleophile) to form an alkene. E subscript 1 end subscript reaction is favoured in compounds in which the leaving group is at secondary open parentheses 2 to the power of ring operator end exponent close parentheses to the power of ´ end exponent or tertiary open parentheses 3 to the power of ring operator end exponent close parentheses position. In E subscript 2 end subscript text end text left parenthesis e l i m i n a t i o n right parenthesis text end text r e a c t i o n s comma text end text t w o text end text s i g m a text end text b o n d s text end text a r e text end text b r o k e n text end text a n d text end text a formed simultaneously. E subscript 2 end subscript reactions occur in one step through a transition state.

E subscript 2 end subscript reactions are most common in haloalkanes (particularly, 1 to the power of ring operator end exponent) and better the leaving group higher is the E subscript 1 end subscript reaction. In E subscript 2 end subscript reactions, both the leaving groups should be antiplanar.
E subscript 1 end subscript cb (Elimination unimolecular conjugate base) reaction involves the removal of proton by. a conjugate base (step 1) to produce carbanion which loses a leaving group to form an alkene (step 2) and is a slow step.
2-Bromobutane on heating with concentrated solution of alcoholic KOH gives major product as:

The removal of two atoms or groups, one generally hydrogen open parentheses H to the power of plus end exponent close parentheses and the other a leaving group open parentheses L to the power of minus end exponent close parentheses resulting in the formation of unsaturated compound is known as elimination reaction.

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E subscript 2 end subscript reactions are most common in haloalkanes (particularly, 1 to the power of ring operator end exponent) and better the leaving group higher is the E subscript 1 end subscript reaction. In E subscript 2 end subscript reactions, both the leaving groups should be antiplanar.
E subscript 1 end subscript cb (Elimination unimolecular conjugate base) reaction involves the removal of proton by. a conjugate base (step 1) to produce carbanion which loses a leaving group to form an alkene (step 2) and is a slow step.
2-Bromobutane on heating with concentrated solution of alcoholic KOH gives major product as:

Chemistry-General
parallel
General
Chemistry-

The removal of two atoms or groups, one generally hydrogen open parentheses H to the power of plus end exponent close parentheses and the other a leaving group open parentheses L to the power of minus end exponent close parentheses resulting in the formation of unsaturated compound is known as elimination reaction.

In E subscript 1 end subscript (elimination) reactions, the C minus L bond is broken heterolytic ally (in step 1) to form a carbocation (as in S subscript N to the power of 1 end exponent end subscript reaction) in which open parentheses L to the power of minus end exponent close) is lost (rate determining step). The carbocation (in step 2) loses a proton from the beta-carbon atom by a base (nucleophile) to form an alkene. E subscript 1 end subscript reaction is favoured in compounds in which the leaving group is at secondary open parentheses 2 to the power of ring operator end exponent close parentheses to the power of ´ end exponent or tertiary open parentheses 3 to the power of ring operator end exponent close parentheses position. In E subscript 2 end subscript text end text left parenthesis e l i m i n a t i o n right parenthesis text end text r e a c t i o n s comma text end text t w o text end text s i g m a text end text b o n d s text end text a r e text end text b r o k e n text end text a n d text end text a formed simultaneously. E subscript 2 end subscript reactions occur in one step through a transition state.

E subscript 2 end subscript reactions are most common in haloalkanes (particularly, 1 to the power of ring operator end exponent) and better the leaving group higher is the E subscript 1 end subscript reaction. In E subscript 2 end subscript reactions, both the leaving groups should be antiplanar.
E subscript 1 end subscript cb (Elimination unimolecular conjugate base) reaction involves the removal of proton by. a conjugate base (step 1) to produce carbanion which loses a leaving group to form an alkene (step 2) and is a slow step.
Isopropyl chloride on heating with concentrated solution of ethanolic KOH gives mainly:

The removal of two atoms or groups, one generally hydrogen open parentheses H to the power of plus end exponent close parentheses and the other a leaving group open parentheses L to the power of minus end exponent close parentheses resulting in the formation of unsaturated compound is known as elimination reaction.

In E subscript 1 end subscript (elimination) reactions, the C minus L bond is broken heterolytic ally (in step 1) to form a carbocation (as in S subscript N to the power of 1 end exponent end subscript reaction) in which open parentheses L to the power of minus end exponent close) is lost (rate determining step). The carbocation (in step 2) loses a proton from the beta-carbon atom by a base (nucleophile) to form an alkene. E subscript 1 end subscript reaction is favoured in compounds in which the leaving group is at secondary open parentheses 2 to the power of ring operator end exponent close parentheses to the power of ´ end exponent or tertiary open parentheses 3 to the power of ring operator end exponent close parentheses position. In E subscript 2 end subscript text end text left parenthesis e l i m i n a t i o n right parenthesis text end text r e a c t i o n s comma text end text t w o text end text s i g m a text end text b o n d s text end text a r e text end text b r o k e n text end text a n d text end text a formed simultaneously. E subscript 2 end subscript reactions occur in one step through a transition state.

E subscript 2 end subscript reactions are most common in haloalkanes (particularly, 1 to the power of ring operator end exponent) and better the leaving group higher is the E subscript 1 end subscript reaction. In E subscript 2 end subscript reactions, both the leaving groups should be antiplanar.
E subscript 1 end subscript cb (Elimination unimolecular conjugate base) reaction involves the removal of proton by. a conjugate base (step 1) to produce carbanion which loses a leaving group to form an alkene (step 2) and is a slow step.
Isopropyl chloride on heating with concentrated solution of ethanolic KOH gives mainly:

Chemistry-General
General
Chemistry-

Karl Ziegler reported that alkenes react with N-bromosuccinimide (NBS) in presence of light to give products resulting from substitution of hydrogen by bromjne at the allylic position, i.e., the position next to the double bond. Let us consider the halogenation of cyclohexene.

Energy level diagram for allylic, vinylic and alkylic, free radicals is .given below:


Above compound on treatment with NBS gives allylic bromides. How many product(s) will be obtained in this reaction?

Karl Ziegler reported that alkenes react with N-bromosuccinimide (NBS) in presence of light to give products resulting from substitution of hydrogen by bromjne at the allylic position, i.e., the position next to the double bond. Let us consider the halogenation of cyclohexene.

Energy level diagram for allylic, vinylic and alkylic, free radicals is .given below:


Above compound on treatment with NBS gives allylic bromides. How many product(s) will be obtained in this reaction?

Chemistry-General
General
Chemistry-

Karl Ziegler reported that alkenes react with N-bromosuccinimide (NBS) in presence of light to give products resulting from substitution of hydrogen by bromjne at the allylic position, i.e., the position next to the double bond. Let us consider the halogenation of cyclohexene.

Energy level diagram for allylic, vinylic and alkylic, free radicals is .given below:

Which of the following sequences is correct about C-H bond energy?

Karl Ziegler reported that alkenes react with N-bromosuccinimide (NBS) in presence of light to give products resulting from substitution of hydrogen by bromjne at the allylic position, i.e., the position next to the double bond. Let us consider the halogenation of cyclohexene.

Energy level diagram for allylic, vinylic and alkylic, free radicals is .given below:

Which of the following sequences is correct about C-H bond energy?

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