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Question

Areactionisspontaneousiffreeenergychange,blank capital delta G,forthereactionisnegative.Thequestionarises,how wecanexplainthespontaneityofreversiblereactions.Letustaketheexampleofdissociationequilibriumof N subscript 2 end subscript O subscript 4 end subscript rightwards harpoon over leftwards harpoon 2 N O subscript 2 end subscript left parenthesis g right parenthesis ThevariationoffreeenergywiththefractionofN2O4dissociatedunderstandardconditions is shown in the figure below:

Thestandardfreeenergychangefortheconversionof1moleofN2O4into2molesofNO2is:

  1. 5.40kJ    
  2. —5.40kJ    
  3. (5.40 +0.84)kJ    
  4. left parenthesis 5.40 plus 2 cross times 0.84 right parenthesis k J    

The correct answer is: 5.40kJ


    DG = G for 2 moles of NO2- G for 1 mole of N2O4 . = 5.40 kJ Hence, (a) is the correct answer.

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