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Question

CuSO4+ excess NH3  X CuSO4+ excess KCl Y To Y, excess KCN is added due to which a highly stable complex results. This complex is:

  1. open square brackets C u left parenthesis C N right parenthesis subscript 4 end subscript close square brackets to the power of 2 minus end exponentdimagnetic    
  2. open square brackets C u left parenthesis C N right parenthesis subscript 6 end subscript close square brackets to the power of 4 minus end exponentdimagnetic    
  3. open square brackets C u left parenthesis C N right parenthesis subscript 4 end subscript close square brackets to the power of 3 minus end exponentparamagnetic    
  4. open square brackets C u left parenthesis C N right parenthesis subscript 6 end subscript close square brackets to the power of 5 minus end exponentparamagnetic    

The correct answer is: open square brackets C u left parenthesis C N right parenthesis subscript 4 end subscript close square brackets to the power of 3 minus end exponentparamagnetic


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    Statement 1:C H subscript 3 end subscript superscript minus end superscript adds to  C=0 group irreversibly but C N to the power of minus end exponent ion adds reversibly
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