Chemistry-
General
Easy

Question

Preparation of alkyl halides in laboratory is least preferred by

  1. Halide exchange    
  2. Direct halogenation of alkanes    
  3. Treatment of alcohols    
  4. Addition of hydrogen halides to alkenes    

The correct answer is: Direct halogenation of alkanes


    Direct halogenation of alkenes is not preferred because in it a mixture of monohalogen, dihalogen, trihalogen and tetrahalogen substituted product is obtained which is difficult to separate.
    e.g. C H subscript 4 end subscript stack ⟶ with C l subscript 2 end subscript on top C H subscript 3 end subscript C l stack ⟶ with C l subscript 2 end subscript on top C H subscript 2 end subscript C l subscript 2 end subscript stack ⟶ with blank to the power of ring operator end exponent C l subscript 2 end subscript blank to the power of ring operator end exponent on top C H C l subscript 3 end subscript stack ⟶ with blank to the power of ring operator end exponent C l subscript 2 end subscript blank to the power of ring operator end exponent on top C C l subscript 4 end subscript

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